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Additional info for Advanced Metallization & Interconnect Systems for Ulsi Applications in 1996: Materials Research Society Conference Proceedings
2+ Figure 2-4. The bis(ethylenediamine)lauratecobalt(rrI) hexafluorophosphate complex. r Figure 2-5. The bis(ethylenediamine)dodecyloxysalicylaldehydechromium(~~ I) hexafluorophosphate complex. Further examples of compounds in which metal complexes form the polar head group of an amphiphilic molecule are based on bipyridine ruthenium(r1) o r rhodium(rr1) complexes (Fig. 2-6). The two types of derivative mainly show cubic (I1) and hexagonal (HI) phases respectively, before an isotropic solution is formed in water.
1- 15 c, e) and tilted (Fig. 1-1 5 c- e) columnar mesophases are possible. The lamellar discotic phase (DL) is defined as a smectic-like organization of molecules. It has been suggested that the molecules are tilted with respect to the layers, but this point does not appear to have been established unequivocally (Fig. 1-16) . Dh (C) Dr (a Dtet (e) Figure 1-15. Schematic representation of five discotic phases: a) N,, nematic discotic; b) N,, columnar nematic; c) D,, discotic hexagonal; d) D,, discotic rectangular, e) D,,,, discotic tetragonal.
Wunderlich and J. Grebowicz, Adv. Polym. Sci. 1984, 60/61, 2.  H. Ringsdorf, B. Schlarb and J. Venzmer, Angew. Chem. Int. Ed. Engl. 1988, 27, 113.  a) A. Leadbetter, Crit. Rep. Appl. Chem. A. Osman, Z. Naturforsch. 1983, 382, 693; c) J. Simon, J. J. Andre and A. Skoulios, New J. Chem. 1986, 10, 295.  D. Demus, Liq. Cryst. 1989, 5, 75 and references cited therein.  J. Charvolin and A. Tardieu, Solid State Phys. Suppl. 1978, 14, 209.  a) N. V. Bykova, Mol. Cryst. Liq. Cryst. 1992, 108, 349-507; b) N.